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Conformity with Standards |
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Sonnenschein Lithium Inorganic Batteries meet
relevant standards like UL 1642 (Underwriters Laboratories), EN
50014 (explosive atmospheres) and military standards as well as
several other application oriented ones like e.g. standards for
safety and alarm equipment, standards for utility meters, and others.
While some of these standards do include performance requirements
for specific
applications, the majority of them deals only with safety aspects
and environmental conditions during storage, transport and use.
No general standards exist for electrical performance of most inorganic
lithium batteries. If reference is made to designations listed in
ANSI C 18.1 (e.g. size AA) or to designations listed in IEC 60086,
parts 1 and 2 (e.g. size R6) this pertains only to the size of the
battery, not to its performance.
Sonnenschein Lithium Batteries are submitted
for qualification according to the requirements of the market. Sonnenschein
Lithium engineers offer their support whenever conformity of a specific
battery with one of the standards mentioned below or with other
standards needs to be established.
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Table
5-1
Safety tests covered by UL standard No. 1642 (revision 1999)
Abbreviations:
NF: no fire, NE: no explosion, NL: no leaking, NO: no overheating
(150 °C), NV: no venting, (R): if requirements are not
met, application is to be restricted, (M): applicable only
to cells intended to be used in multicell applications such
as battery packs.
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5.1 Underwriters Laboratories
Underwriters Laboratories Inc. (UL) is a non-profit
organization whose objective is to set standards for product safety
and supervise compliance with these standards by manufacturers of
components or equipment.
Sonnenschein Lithium Batteries comply with
the Ul-standards as described here and in the relevant product data
sheets. The following UL documentation refers to these batteries.
UL Standard for Safety
Component Category No.
File No. |
No.1642, Lithium
Batteries
BBCV2
MH12827 |
The safety tests covered by this standard are
summarized in table 5-1. The standard
also describes minimum requirements for casing, marking, protection
circuits against abnormal charging and a few other subjects.
Protection against charging
Whenever lithium batteries are not the single power source in a
circuit the following measures recommended by Underwriters Laboratories
are relevant. The cells should not be connected in series with an
electrical power source that would increase the forward current
through the cells. The circuit for these cells shall include one
of the following (please refer to paragraph 7.1 for a circuit diagram):
A. Two suitable diodes or the equivalent in series
with the cells to prevent any reverse (charging) current. The second
diode is used to provide protection in the event that one should
fail. Quality control, or equivalent procedures, shall be established
by the device manufacturer to ensure the diode polarity is correct
for each unit, or
B. A blocking diode or the equivalent to prevent
any reverse (charging) current and a resistor to limit current in
case of a diode failure. The resistor should be sized to limit the
reverse (charging) current to the maximum values given in the Sonnenschein
Lithium Product Data Catalogue.
It should be noted here that the resistor R should
be dimensioned such that I = Un / R does not exceed the given maximum
values, Un being the nominal voltage of the battery.
Battery Replacement
Lithium batteries of this category are technician-replaceable unless
it is noted in the data sheets or in the UL component listing that
a battery is user-replaceable.
A technician-replaceable battery is intended
for use in a product in which service and replacement of the battery
will be done only by a person who has been trained to service and
repair the product. A battery that is intended for use in a product
in which service and replacement of the battery may be done by the
user will be categorized as user-replaceable.
With respect to user-replaceable lithium batteries
of any chemical system, UL requires several procedures to ensure
that important safety information reaches the end user.
The packaging for a user-replaceable battery
shall be marked with the word "CAUTION" and the following
or equivalent statements: "Risk of fire and burns. Do not recharge,
disassemble, heat above 100°C, or incinerate. Keep battery out
of reach of children and in original package until ready to use.
Dispose of used batteries promptly."
The end product with a user-replaceable lithium
battery shall be permanently marked adjacent to the battery: "Replace
battery with (battery manufacturer's name or end product manufacturer's
name, part number) only. Use of another battery may present a risk
of fire or explosion. See owner's manual for instructions."
or "See operating or maintenance instructions for type of battery
to be used."
The operating or maintenance instructions
shall provide the user with complete instructions as to how to replace
and dispose of a used battery. This information shall include the
following:
a) A warning notice stating the following or
the equivalent: "CAUTION - The battery used in this device
may present a risk of fire or chemical burn if mistreated. Do not
recharge, disassemble, heat above 100°C, or incinerate. Replace
battery with (battery manufacturer's name or end product manufacturer's
name and part number) only. Use of another battery may present a
risk of fire or explosion."
b) Complete instructions as to how to replace
the battery ending with the statement: "Dispose of used battery
promptly. Keep away from children. Do not disassemble and do not
dispose of in fire."
5.2 Explosive atmospheres
Requirements for batteries to be used in electrical
apparatus for potentially explosive atmospheres are published in
the European standard EN 50014. Sonnenschein Lithium can support
manufacturers of such apparatus by providing temperature and current
data of Sonnenschein Lithium Batteries during short circuit at 40
°C and 70 °C. Most Sonnenschein Lithium Batteries comply
with temperature class T4 of this standard, which means they can
be used in apparatus for potentially explosive atmospheres with
an ambient temperature of up to +70 °C. Please contact Sonnenschein
Lithium for more information on this subject.
5.3 Military standards
Because of their outstanding features with respect to environmental
conditions of storage and use, lithium thionyl chloride batteries
have found the interest of military users.
A special product - a reserve type cell - was
developed by Sonnenschein Lithium for applications with a short
or medium operating period after extremely long storage. Storage
times of more than 8 years at +70 °C (!) have been achieved
with this type of battery with no degradation of activation time
and operating life. This product as well as several other batteries
of the Sonnenschein Lithium basic series have passed environmental
and safety tests described in the following military standards:
MIL-B-49461 (ER)
MIL-STD-202
MIL-STD-331
MIL-STD-810
VG 96915 |
USA Military specification
for non-rechargeable lithium thionyl chloride batteries
USA Military standard: Test methods for electronic and electrical
component parts
USA Military standard: Fuze and fuze components, Environmental
and performance tests for
USA Military standard: Environmental test methods and engineering
guidelines
GER Defence material standard non-rechargeable batteries |
Tests described in these standards and passed
by Sonnenschein Lithium Batteries include the subjects and major
test conditions summarized in table 5-2. Complete test descriptions
and results are available upon request.
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Table 5-2
Military standard tests passed by Sonnenschein Lithium Inorganic
Batteries
Abbreviations:
ND: no degradation, NF: no fire, NE: no explosion,
NL: no leakage, NV: no venting, FS: function of safety feature
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