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Storage, Transport, Handling, and Disposal |
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8.1 General Precautions
Sonnenschein Lithium Batteries are primary power
sources with high energy content. They are designed to represent
the highest possible degree of safety. They may, however, present
a potential hazard if they are abused electrically or mechanically.
This is in most circumstances associated with the generation of
excessive heat. The internal pressure may cause the cell case to
rupture.
Thus the following basic precautions should
be observed when handling and using Sonnenschein
Lithium Batteries:
Caution
- Do not short-circuit
- Do not recharge
- Do not overdischarge
- Do not incinerate
- Do not expose to temperatures beyond the specified
temperature range
- Do not crush or puncture
- Do not open cells, do not disassemble battery
packs
- Do not expose contents to water
- Do not connect with false polarity
- Do not weld or solder to the battery's body
For general safety considerations please refer
to chapter 4. Additional precautions for the assembly of battery
packs are given in paragraph 7.3.
8.2 Storage
General Conditions
Batteries should be stored in rooms with generally low temperature
and low humidity levels. While it is not essential that these storage
areas be temperature and humidity controlled, temperatures should
generally be kept below 35°C and storage areas should be well
ventilated.
Storage temperatures above 75°C should be
avoided.
Insulation
Lithium batteries should be stored in their original packaging materials.
This will eliminate unintentional shorting.
Do not store batteries in conductive anti-static
bags or foam unless the resistivity of the material exceeds 1 MΩ.
Batteries should not be placed on or covered with metallic or otherwise
conductive material.
Fire protection
Batteries should be stored away from any flammable material in the
storage area.
Fire extinguishers for metal fire (class D) are
preferred. Do not attempt to extinguish fires with small amounts
of water, sand, or with carbon dioxide extinguishers.
A Technical Notice with further recommendations
is available upon request.
8.3 Transport Regulations
Lithium Batteries are generally classified as
dangerous goods according to UN 3090 (lithium batteries) and UN
3091 (lithium batteries contained in equipment or packed with equipment).
The table on the next page
gives a brief summary of the regulations. However,
most Sonnenschein Lithium Batteries are not
subject to the transport regulations because they meet the provisions
listed hereafter:
- Cells contain no more than 0.5 g of lithium
or lithium alloy.
- Battery packs contain an aggregate quantity
of no more than 1 g of lithium or lithium alloy.
- Sonnenschein Lithium Batteries, besides SL-790,
contain not more than 5 g of lithium per cell and not more than
25 g per battery pack and have passed the tests required by the
UN manual of tests and criteria. Therefore, they are not subject
to the regulations, provided the following general rules are observed:
- Each cell is hermetically sealed.
- Batteries are separated from each other in
the package so as to prevent shorting.
- Battery packs are packed in strong outside
packaging (except when installed in electronic devices).
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ADR:
IATA DGR:
ICAO:
IMDG Code:
RID:
UN:
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Table
Transport regulations for Sonnenschein Lithium Batteries.
These regulations apply to type SL-790 (lithium content 10
g) and to battery packs containing more than 1 cell. Battery
packs need to be tested according to the UN manual of tests
and criteria in order to be attributed to class 9.
It is necessary to refer to the listed regulations and instructions
for detailed information. They are reviewed on a regular basis.
The table is based on the 2000 revisions.
The applicable documents are:
European Agreement concerning the International Carriage of
Dangerous Goods by
Road, International Air Transport Association, Dangerous Goods
Regulations
International Civil Aviation Organization, Technical Instructions
for the Safe Transport
of Dangerous Goods by Air.
International Maritime Dangerous Goods Code
International Statutory Order on the Conveyance of Dangerous
Goods by Rail
United Nations Recommendations on the Transport of Dangerous
Goods
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Class 9 label, reduced size, black on white
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Handling Label for Cargo Aircraft Only,
reduced size,
black on orange
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8.4 Mounting
General
In most cases, Sonnenschein Lithium Batteries are soldered to the
PC-board. Replaceable batteries usually are equipped with connectors
and hook and loop tapes to ensure quick and safe mounting. Other
mounting techniques may include hot melt glue or plastic tapes to
secure the battery to the PC-board. Solder pins and tags usually
are not suitable as battery holders, especially with the cells of
size C and larger.
Sonnenschein Lithium Batteries comply with IEC
standard 68-2-21 and ESA specification PSS-01-708. This means that
solder pins and tags can withstand a tensile force of 10 N in the
direction of their axis. Pins can be bent with an inside radius
of 0.8 mm at a minimum distance of 2.5 mm. Alternative geometries
should be used when smaller distances are needed (Fig. 8-3).
When the battery is mounted on the PC-board,
it should not make contact to the conductive mat that is used to
eliminate static electricity as this may cause a discharge circuit
and lead to premature depletion.
Hand Soldering
Use only batteries that have been provided by Sonnenschein Lithium
with solder tags or wire leads, when it is required to make soldered
connections to them.
Caution
- Do not attempt to solder directly to the cell
case or terminal.
- Keep the soldering time as short as
possible, below 10 seconds.
- Use appropriate protection during pretinning.
Batteries must not be dropped in tin baths.
Wave Soldering
The Sonnenschein Lithium Battery is a safe power source. It has
moderate impedance and, when operating at temperatures up to 75°C,
it can withstand a continuous short-circuit without any safety problems,
the battery will not explode, crack or leak. It is therefore, in
principle, suitable for wave soldering. However, the following recommendations
should be observed:
Sonnenschein Lithium flat cells are provided
with nickel pins and may be wave soldered.
Sonnenschein Lithium bobbin type cells can be
provided with axial wire leads or with nickel solder tags. The small
cells may be wave soldered. The big cells should be hand soldered
for reasons of safety.
If a battery is dropped into the solder
bath, or if it is held above the bath for a long period, it might
rupture, due to overheating and consequent melting of the lithium
metal.
Caution
- Secure the battery to the printed circuit
board before introducing it into the wave soldering process (including
pre-heating and drying).
- Do not overheat. Refer to table
8-4 for recommendations.
- Provide a cover over the soldering zone when
lithium cells are being wave soldered.
- Do not use reflow soldering when mounting
cells.
Cleaning processes are not standardized. Therefore
compatibility may have to be established case by case. Water should
not get trapped underneath the jacket. Organic solvents may have
an effect on the readability of markings or on the softening agent
of the jacket. Please contact Sonnenschein Lithium for recommendation
of approved processes.
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Figure 8-3
Minimum bend of pins, alternative geometry |
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Table 8-4
Recommendations for wave soldering |
8.5 Disposal
The disposal or recycling of batteries is regulated
by each European country. In each country, the manufacturers, importers
and users are responsible for the proper disposal.
The European Community (EC) has issued two directives,
91/157/EEC and 93/86/EEC. These directives are implemented by each
member country of the EC independently and in a different way.
In accordance with these directives, Sonnenschein
Lithium Batteries do not contain dangerous substances. The reaction
products are inorganic and do not represent environmental risks
once the decomposition process has terminated.
For batteries bought from Sonnenschein Lithium,
a disposal service is offered upon customer request.
A Technical Notice with further recommendations
is available upon request.
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